منابع مشابه
1-(3-Bromopropoxy)-4-chlorobenzene
In the mol-ecule of the title compound, C(8)H(8)BrClO, the Cl atom lies slightly out of the aromatic ring plane [displacement = 0.072 (3) Å]. In the crystal structure, a π-π contact between the phenyl rings [centroid-centroid distance = 3.699 (3) Å] may stabilize the structure. There also exists a C-H⋯π contact between the methyl-ene group and the chloro-phenyl ring.
متن کاملStudies on the reactivity of cis-4-benzyloxy-1,2-epoxycyclohexane
The reaction course of the selenation-oxidation-elimination sequence carried out from cis-4-benzyloxy-1,2-epoxycyclohexane (cis-1) is studied. Contrary to literature precedents, this transformation leads to an unexpected diastereomeric cyclohexenol, whose formation can be interpreted by stereoelectronic grounds. In addition, the base induced rearrangement of cis-1 with lithium amide bases is al...
متن کاملSynthesis of benzyl esters using 2-benzyloxy-1-methylpyridinium triflate.
Triethylamine (Et3N) mediates esterification reactions between the title reagent (1) and carboxylic acids. Alcohols, phenols, amides, and other sensitive functionality are not affected; a dual role for Et3N as a promoter and a scavenger is postulated. Benzyl esters are obtained from substrates including amino acid and sugar derivatives.
متن کاملThe Solvation and Dissociation of 4‐Benzylaniline Hydrochloride in Chlorobenzene
A reaction scheme is proposed to account for the liberation of 4-benzylaniline from 4-benzylaniline hydrochloride, using chlorobenzene as a solvent at a temperature of 373 K. Two operational regimes are explored: “closed” reaction conditions correspond to the retention of evolved hydrogen chloride gas within the reaction medium, whereas an “open” system permits gaseous hydrogen chloride to be r...
متن کاملEthyl 2-[4-(benzyloxy)anilino]-4-oxo-4,5-dihydrofuran-3-carboxylate
In the title compound, C(20)H(19)NO(5), the dihydro-furan ring is almost planar [maximum deviation of 0.021 (2)°] and makes dihedral angles of 28.1 (7) and 54.5 (5)° with the benzyl and phenyl-amino rings, respectively. The mol-ecular packing is stabilized by intra-molecular N-H⋯O hydrogen bonds and inter-molecular C-H⋯O inter-actions.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2009
ISSN: 1600-5368
DOI: 10.1107/s160053680905096x